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I use it all the time on legendaries, I have NO patience for those types of battles using an Ultra/Timer Ball lol
same here. tbh, It's impossible to catch a legendary without a Master ball. The other ones don't work for me. xD
I also just like you though cause I just dont like to go and find those pokemon that roaming like latias.. At the first meet those pokemon ,if I dont think too much at that time, I just throw a master ball..gotcha catch it ..In X/Y I used it on Mewtwo because I was lazy.
I usually tend to use it on roaming legendaries, though. I would never waste it on the main game legendary.